Product ID:4 OZ DEODORANT CAKES, 5104
MSDS Date:02/11/1991
FSC:8520
NIIN:00N020729
MSDS Number: BLVQH

I SCHNEID INC

1429 FAIRMONT AVE NW
ATLANTA, GA 30381-4601
US

Emergency Phone: 404-351-4705

Info Phone: 404-351-4705

Cage: IO057

SCHNEID I INC DBA SAN-MAR LABORATORIES

93188 ATLANTA, GA 30381-0188 US

Telephone: 404-351-4705

Cage: 0C5M3

BENZENE, P-DICHLORO-;(PARADICHLOROBENZENE)

CAS: 106-46-7

RTECS: CZ4550000

Fraction By Weight: 100%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM,A3 9394

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:IRRITATION TO EYES AND UPPER
RESPIRATORY TRACT, CENTRAL NERVOUS SYSTEM DEPRESSION, LIVER AND
KIDNEY INJURY. CHOLORCARBON MATL HAVE PRODUCED SENSITIZATION OF THE
MYOCARDIUM TO EPINEPHRINE IN LAB ANIMAL S AND COULD HAVE A SIMILAR
EFFECT IN HUMANS ADRENOMIMETICS(E.G. EPINEPHRINE)MAY BE
CONTRA-INDICATED EXCEPT (SIGNS & SYMP
Explanation of Carcinogenicity:PARADICHLOROBENZENE: IARC GROUP 2B, NTP
KNOWN ANIMAL CARCINOGEN/SUSPECTED HUMAN CARCINOGEN.
Effects of Overexposure:HEALTH HAZ:FOR LIFE-SUSTAINING USES IN HUMANS
ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS..
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN: FLUSH W/WATER, IF IRRIT PERSISTS CALL MD. EYES: FLUSH
W/WATER FOR AT LEAST 15 MIN. IF IRRIT PERSISTS, CALL MD. INGEST: IF
CONSC, DRINK A QT OF WATER & TAKE IMMED TO A MD. DO NOT INDUCE
VOMIT. IF UNCON OR IN CONVULSIONS, TAKE IMMED TOMD/HOSPITAL. DO
NOT GIVE ANYTHING TO AN UNCON PERSON. INHAL: REMOVE TO FRESH AIR.
IF NOT BRTHING, GIVE ARTF RESP-O2 IF NEC, CONTACT MD. (SUPP DATA)

Flash Point Method:CC
Flash Point:148F,64C
Extinguishing Media:DRY CHEMICAL, FOAM, CO2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED, PRESSURE DEMAND SCBA
AND FULL PROT EQUIP . POSSIBLE EXPOSURE TO HYDROGEN CHLORIDE GAS
AND POSSIBLE TRACES OF PHOSGENE.
Unusual Fire/Explosion Hazard:BURNS TO FORM TOXIC AND CORROSIVE
HYDROGEN CHLORIDE GAS AND POSSIBLE TRACES OF PHOSGENE.

Spill Release Procedures:REMOVE UNPROT PERS FROM AREA OF SPILL, PROVIDE
MAX VENT & REMOVE ALL IGNIT SOURCES. ONLY PERS EQUIPPED W/PROPER
RESP & EYE/SKIN PROT PERMITTED IN AREA.CAREFULLY SHOVEL/SWEEP UP
SPILLED MATL, PLACE IN CLOSED CNTRS. MAINTAIN VENT UNTIL ALL
VAPS(SUP DAT
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID TEMP EXTREMES.NO SMOKING IN AREA
OF USE. DO NOT USE IN GENERAL VICINITY OF ARC WELDING,OPEN FLAMES
OR HOT SURFACES.HEAT AND/OR (SEE SUPP DATA)
Other Precautions:AVOID BREATHING VAPORS. AVOID EYE EXPOSURE. AS WITH
ALL CHEMICALS, USE DUE CARE ACCORDING TO LABEL INSTRUCTIONS AND
PRECAUTIONS.

Respiratory Protection:NONE NORMALLY - NIOSH/MSHA APPROVED FULL FACE
MASK FITTED WITH ORGANIC VAPOR CANISTER FOR CONCENTRATES OVER 75
PPM.
Ventilation:MECHANICAL, (GENERAL), SUFFICIENT TO CONTROL VAPORS TO 75
PPM OR LESS.
Protective Gloves:POLYETHYLENE,NEOPRENE,POLYVINYL ALCOHOL
Eye Protection:CHEMICAL WORKERS GOGGLES
Other Protective Equipment:CLEAN AND PROTECTIVE CLOTHING TO AVOID SKIN
EXPOSURE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPILL PROC:HAVE BEEN ELIMINATED THEN THOROUGHLY FLUSH AREA OF SPILL
WITH WATER.MTRL SHOULD BE RECOVERED AND/OR REPROCESSED. FIRST AID
PROC: NOTE TO MD: ADMIN OF ADRENALIN MAY BE CONTRAINDICATED FOR OV
EREXPOSURE TO PARADICHLOROBENZENE. STORAGE PREC:AND/ OR UV
RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE(FP N

HCC:T4
Boiling Pt:B.P. Text:345F,174C
Vapor Pres:76
Vapor Density:5.1(AIR=1)
Spec Gravity:1.248
pH:7
Solubility in Water:0.008 GM/100 GM
Appearance and Odor:LIGHTLY COLORED AND PERFUMED SOLID.
Percent Volatiles by Volume:100%

Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:OPEN FLAMES, HOT GLOWING SURFACES OR
ELECTRIC AREAS.
Hazardous Decomposition Products:HYDROGEN CHLORIDE AND POSSIBLE TRACES
OF PHOSGENE.

Waste Disposal Methods:BURN IN APPRVD INCINERATOR/BURIAL IN PERMITTED
HAZARDOUS WASTE MANAGEMENT FACILITY. CARE MUST BE TAKEN WHEN
USING/DISP OF CHEM MATL AND/OR THEIR CNTRS TO PREVENT ENVIRON
CONTAM. DISPOSE OF I/A/W FEDER AL, STATE AND LOCAL REGULATIONS.

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expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.